Abstract:By refluxing with cuprous handes in acetonitrile trialkyl phosphites can be directly converted into the corresponding dialkyl alkylphosphonate. The conversion of trialkyl phosphites with cuprous iodidees is more favorable than with cuprous chloride; The activity of the alkyl group for the rearrangement is in the order of Me>Et>Butyl.
收稿日期: 1996-01-25
引用本文:
肖海燕,朱传方. 无卤代烷下亚磷酸三烷基酯的重排[J]. , 1996, 35(1): 0-0.
肖海燕,朱传方. TRIALKYL PHOSPHITES DIRECTLY CONVERTED TO DIALKYL ALKYLPH-OSPHONATES IN THE ABSENCE OF ALKYL HALIDES. , 1996, 35(1): 0-0.