Abstract:The products distribution of liquid isomerization of 2,10-epoxypiane in the presence of NH4 NO3 was studied in this paper. The influences of different catalyst systems, solvents and the amount of solvent on the isomerization were investigated. It is discovered that perilly alcohol can be obtained in a high selectivity by NH4NO3 which is absorbed on silica gel in CH3NO2, but myrtenol was obtained as the main product catalyzed by NH4NO~ in CHCl3 and CCl3CH3.
收稿日期: 2006-03-25
引用本文:
詹小雄,李谦和,周建良,王乐夫. 硝酸铵催化的2,10-环氧蒎烷液相重排反应规律研究[J]. , 2006, 45(3): 0-0.
詹小雄,李谦和,周建良,王乐夫. Liquid-phase isomerization of 2,10-epoxypinane catalyzed by NH4NO3. , 2006, 45(3): 0-0.